ZINC
NUTRITION
Zinc is one of the essential micronutrients required for optimum crop
growth. Plants take up zinc in its divalent form. At this time it still
remains unclear whether this uptake is facilitated as diffusion through
membranes specific for zinc ion or whether it is mediated by specific
transporter(s). It has been concluded that both mechanisms operate,
and about 90.5% of the total zinc required by plants moves towards the
roots by diffusion. This lateral movement of zinc is highly dependent
upon the soil moisture, and this may be the reason why, particularly
in arid and semi-arid areas, zinc deficiency is more frequently seen.
The vast majority of zinc is present in the lattice structure of the
soil and therefore, unavailable to meet the plant’s nutritional
requirements. Available soil zinc is dissolved in the soil solution
in ionic or complex form and may be found on the exchange sites of clay
minerals and organic matter. Zinc can also be found as adsorbed divalent
cation, zinc hydroxide, or zinc chloride. The solubility of zinc is
highly dependent upon soil pH. Presence of calcium carbonate decreases
the availability of zinc due to higher soil pH. The poor zinc availability
in alkaline calcareous soils is precisely due to the formation of zinc
carbonate. High levels of soil phosphorus are also commonly responsible
for zinc deficiency. Presence of excess amount of copper can also reduce
zinc availability because the absorption of both cations is through
the same mechanism, which causes interference in the uptake. On the
contrary, application of magnesium can enhance zinc availability and
uptake by the roots.
Zinc is transported in the xylem tissues from the roots to the shoots.
However, high levels of zinc have been detected in the phloem tissues,
which indicates that zinc moves through both transport tissues, and
maybe remobilisation of zinc towards the grain during ripening. Substantial
translocation of zinc takes place from the older leaves to the younger
ones during grain development phase. Plants deficient in nitrogen do
not show the retranslocation of zinc from the older leaves, indicating
that the deficiency symptoms of zinc are more pronounced in the nitrogen
deficient plants.
Using zinc in the fertility program
Both soil and leaf tissue tests are accurate evaluations of zinc requirements.
If a crop is “zinc responsive” and a high yield program
is being used, some zinc is often inexpensive insurance for the higher
yield goals. Zinc is sometimes applied broadcast to correct the zinc
level in soils in one treatment. Zinc oxide and oxy-sulphates are slow
release forms for build-up purposes. However, for in- row applications
or for immediate uptake zinc sulphate or chelated and /or complexed
zinc must be sprayed or applied to the soil. As indicated above, zinc
must be present in soil solution in soluble form, a form that can only
be possible with the application of zinc sulphate or complexed zinc.
Zinc oxide, though, a very high analysis source of zinc, is not soluble
in water, consequently the zinc is not released in the soil solution
for roots to absorb. Moreover, spray application of zinc oxide on a
standing crop will not be profitable as only a very minute percentage
of applied zinc can penetrate the leaf tissue. Rest of the zinc goes
waste during threshing as it still adheres to the foliage. This may
limit the zinc requirement of a crop and reduce the yields. Zinc oxide
forms a thin film over the leaf surface, which may reduce the canopy
light interception and consequently reduce photosynthesis. Zinc oxide
should always be applied through the soil for correcting zinc pool for
the subsequent crops. However, the amount of zinc released depends upon
the subsequent soil moisture conditions, as dry topsoil can still limit
the zinc availability for the next crop. For immediate requirements
the growers should use a soluble form of zinc such as Smartrace Zinc
or zinc sulphate. Zinc applied using these fertilisers is rapidly absorbed
by the leaves, and is translocated to the grain. The growers must correctly
ascertain the amount of zinc required by the crop as excessive amounts
of zinc sulphate can cause severe leaf fall.
Zinc deficiency
Deficiency of zinc is widespread among crops grown in calcareous soils
and highly weathered acid soils. The deficiencies in the calcareous
soils are often associated with iron deficiency as well. Zinc deficiency
symptoms in wheat appear between three to five weeks after emergence,
and in rice about two to four weeks after transplanting. In severely
deficient zinc soils, wheat and corn germination is poor and in these
situations, seed treatment with Smartrace Zinc-Manganese or Smartrace
Zinc can substantially improve seed germination and seedling vigour.
Spray application of soluble zinc such as Smartrace Zinc during grain
filling can improve the zinc level in seeds for better germination in
such soils. The deficiency symptoms of zinc are;
1. dusty brown spots of upper leaves of stunted plants
2. uneven plant growth and patches of poorly established plants in the
field
3. decreased tillering, spike or spikelet sterility and interveinal
chlorosis on l eaves
4. dicots shows drastic decrease in leaf size, loss of lustre and shoots
die off.
5. premature leaf fall, chiefly in apples.
Metabolic roles of zinc
Zinc plays an important role in many biochemical reactions within the
plants. Plants such as maize and sorghum and sugarcane shows reduced
photosynthetic carbon metabolism due to zinc deficiency. Zinc modifies
and/or regulates the activity of cabonic anhydrase, an enzyme that regulates
the conversion of carbon dioxide to reactive bicarbonate species for
fixation to carbohydrates in these plants. Zinc is also a part of several
other enzymes such as superoxide dismutase and catalase, which prevents
oxidative stress in plant cells. Following are the various other roles
of zinc in plants;
1. production of auxin, an essential growth hormone
2. regulates starch formation and proper root development
3. formation of chlorophyll and carbohydrates
4. enable plants to withstand lower air temperatures
5. helps in the biosynthesis of cytochrome; a pigment, and maintains
plasma membrane integrity, and synthesis of leaf cuticle.
While zinc is essential for every plant, these crops have been found
to be especially responsive: corn, rice, wheat, sweet corn, cotton,
citrus, most orchard crops and sorghum.